Stepwise synthesis of a mixed valent Fe(II)-Fe(III) complex in cast multibilayer films

Nobuo Kimizuka, Toyokazu Handa, Toyoki Kunitake

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A mixed valent complex of μ-cyanide Fe(II)-Fe(III) was prepared by stepwise synthesis at the interlayer of multibilayer cast films. The Fe(II)-Fe(III) complex showed altered absorption characteristics in the interbilayer from those of bulk Prussian Blue, probably due to its geometrically confined structure.

Original languageEnglish
Pages (from-to)189-194
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume276-277
Publication statusPublished - Dec 1 1996
Externally publishedYes

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Cyanides
cyanides
casts
interlayers
synthesis
ferric ferrocyanide

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

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abstract = "A mixed valent complex of μ-cyanide Fe(II)-Fe(III) was prepared by stepwise synthesis at the interlayer of multibilayer cast films. The Fe(II)-Fe(III) complex showed altered absorption characteristics in the interbilayer from those of bulk Prussian Blue, probably due to its geometrically confined structure.",
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AU - Handa, Toyokazu

AU - Kunitake, Toyoki

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Y1 - 1996/12/1

N2 - A mixed valent complex of μ-cyanide Fe(II)-Fe(III) was prepared by stepwise synthesis at the interlayer of multibilayer cast films. The Fe(II)-Fe(III) complex showed altered absorption characteristics in the interbilayer from those of bulk Prussian Blue, probably due to its geometrically confined structure.

AB - A mixed valent complex of μ-cyanide Fe(II)-Fe(III) was prepared by stepwise synthesis at the interlayer of multibilayer cast films. The Fe(II)-Fe(III) complex showed altered absorption characteristics in the interbilayer from those of bulk Prussian Blue, probably due to its geometrically confined structure.

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