Stepwise synthesis of fullerene cyclopentadienide R5C60- and indenide R3C60-. An approach to fully unsymmetrically substituted derivatives

Masaya Sawamura, Motoki Toganoh, Kazuhiro Suzuki, Atsushi Hirai, Hitoshi Iikura, Eiichi Nakamura

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

(Equation presented) Fullerene cyclopentadienide (PhCH2)2Ph3C60- and indenide (PhCH2)2PhC60-, each bearing two different organic groups, were efficiently synthesized through regioselective reactions of 1,4-(PhCH2)2C60 with an organocopper reagent (PhMgBr/CuBr-SMe2) or a Grignard reagent (PhMgBr) followed by deprotonation with KOtBu.

Original languageEnglish
Pages (from-to)1919-1921
Number of pages3
JournalOrganic letters
Volume2
Issue number13
DOIs
Publication statusPublished - Jun 29 2000

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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