Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134

Makoto Sasaki; Nobuaki Matsumori; Michio Murata; Kazuo Tachibana; Takeshi Yasumoto

doi:10.1016/0040-4039(95)01973-L

Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134

Makoto Sasaki, Nobuaki Matsumori, Michio Murata, Kazuo Tachibana, Takeshi Yasumoto

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in ¹H and ¹³C NMR spectra. This result completed Stereochemical assignments of the whole molecule except for side chains.

Original language	English
Pages (from-to)	9011-9014
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	49
DOIs	https://doi.org/10.1016/0040-4039(95)01973-L
Publication status	Published - Dec 4 1995
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(95)01973-L

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title = "Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134",

abstract = "The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed Stereochemical assignments of the whole molecule except for side chains.",

author = "Makoto Sasaki and Nobuaki Matsumori and Michio Murata and Kazuo Tachibana and Takeshi Yasumoto",

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AU - Sasaki, Makoto

AU - Matsumori, Nobuaki

AU - Murata, Michio

AU - Tachibana, Kazuo

AU - Yasumoto, Takeshi

PY - 1995/12/4

Y1 - 1995/12/4

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AB - The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed Stereochemical assignments of the whole molecule except for side chains.

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JF - Tetrahedron Letters

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ER -

Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134

Abstract

All Science Journal Classification (ASJC) codes

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