Stereochemical assignment of the C35-C39 Acyclic linkage in maitotoxin: completion of stereochemical determination of C15-C134

Makoto Sasaki, Nobuaki Matsumori, Michio Murata, Kazuo Tachibana, Takeshi Yasumoto

Research output: Contribution to journalArticlepeer-review

41 Citations (Scopus)

Abstract

The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed Stereochemical assignments of the whole molecule except for side chains.

Original languageEnglish
Pages (from-to)9011-9014
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number49
DOIs
Publication statusPublished - Dec 4 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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