The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed Stereochemical assignments of the whole molecule except for side chains.
All Science Journal Classification (ASJC) codes
- Drug Discovery
- Organic Chemistry