Abstract
The treatment of O-glycoside with alcohol in the presence of montmorillonite K10 clay and 4-Å MS yields the 1,4-aryl migration product with a 1,2-cis-phenyl C-glycoside scaffold and a chiral silyl moiety with high stereoselectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 2064-2068 |
| Number of pages | 5 |
| Journal | Synlett |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Aug 1 2008 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
Cite this
Stereoselective 1,4-phenyl migration from silicon to carbon in α-siloxy cyclic acetal systems : A concise synthesis of 1,2-cis-phenyl C-glycoside and enantioenriched silanol. / Nakazaki, Atsuo; Usuki, Junji; Tomooka, Katsuhiko.
In: Synlett, No. 13, 01.08.2008, p. 2064-2068.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Stereoselective 1,4-phenyl migration from silicon to carbon in α-siloxy cyclic acetal systems
T2 - A concise synthesis of 1,2-cis-phenyl C-glycoside and enantioenriched silanol
AU - Nakazaki, Atsuo
AU - Usuki, Junji
AU - Tomooka, Katsuhiko
PY - 2008/8/1
Y1 - 2008/8/1
N2 - The treatment of O-glycoside with alcohol in the presence of montmorillonite K10 clay and 4-Å MS yields the 1,4-aryl migration product with a 1,2-cis-phenyl C-glycoside scaffold and a chiral silyl moiety with high stereoselectivity.
AB - The treatment of O-glycoside with alcohol in the presence of montmorillonite K10 clay and 4-Å MS yields the 1,4-aryl migration product with a 1,2-cis-phenyl C-glycoside scaffold and a chiral silyl moiety with high stereoselectivity.
UR - http://www.scopus.com/inward/record.url?scp=49749101271&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=49749101271&partnerID=8YFLogxK
U2 - 10.1055/s-2008-1077953
DO - 10.1055/s-2008-1077953
M3 - Article
AN - SCOPUS:49749101271
SP - 2064
EP - 2068
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 13
ER -