Stereoselective esterification of dl-menthol by polyurethane-entrapped lipase in organic solvent

Satoru Koshiro; Kenji Sonomoto; Atsuo Tanaka; Saburo Fukui

doi:10.1016/0168-1656(85)90055-0

Stereoselective esterification of dl-menthol by polyurethane-entrapped lipase in organic solvent

Satoru Koshiro, Kenji Sonomoto, Atsuo Tanaka, Saburo Fukui

Systems Biology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Stereospecific esterification of dl-menthol was studied by the use of immobilized lipase in an adequate water-saturated organic solvent system. Lipase from Candida cylindracea immobilized by entrapment with urethane prepolymers and 5-phenylvaleric acid as the acyl donor were chosen based on the stereoselectivity and the yield of l-menthyl ester. Water-saturated cyclohexane or isooctane was found to be the most suitable solvent system. Entrapment significantly enhanced the operational stability of lipase.

Original language	English
Pages (from-to)	47-57
Number of pages	11
Journal	Journal of Biotechnology
Volume	2
Issue number	1
DOIs	https://doi.org/10.1016/0168-1656(85)90055-0
Publication status	Published - Feb 1985

All Science Journal Classification (ASJC) codes

Biotechnology
Bioengineering
Applied Microbiology and Biotechnology

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10.1016/0168-1656(85)90055-0

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abstract = "Stereospecific esterification of dl-menthol was studied by the use of immobilized lipase in an adequate water-saturated organic solvent system. Lipase from Candida cylindracea immobilized by entrapment with urethane prepolymers and 5-phenylvaleric acid as the acyl donor were chosen based on the stereoselectivity and the yield of l-menthyl ester. Water-saturated cyclohexane or isooctane was found to be the most suitable solvent system. Entrapment significantly enhanced the operational stability of lipase.",

author = "Satoru Koshiro and Kenji Sonomoto and Atsuo Tanaka and Saburo Fukui",

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AU - Koshiro, Satoru

AU - Sonomoto, Kenji

AU - Tanaka, Atsuo

AU - Fukui, Saburo

PY - 1985/2

Y1 - 1985/2

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AB - Stereospecific esterification of dl-menthol was studied by the use of immobilized lipase in an adequate water-saturated organic solvent system. Lipase from Candida cylindracea immobilized by entrapment with urethane prepolymers and 5-phenylvaleric acid as the acyl donor were chosen based on the stereoselectivity and the yield of l-menthyl ester. Water-saturated cyclohexane or isooctane was found to be the most suitable solvent system. Entrapment significantly enhanced the operational stability of lipase.

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Stereoselective esterification of dl-menthol by polyurethane-entrapped lipase in organic solvent

Abstract

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