Stereoselective multimodal transformations of planar chiral 9-membered diallylic amides

Katsuhiko Tomooka, Masaki Suzuki, Maki Shimada, Runyan Ni, Kazuhiro Uehara

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Intermolecular reactions of planar chiral 9-membered diallylic amides provide a variety of bicyclic compounds with central chiralities in a stereospecific fashion with high group selectivity. Lewis-acid-promoted intramolecular reactions of the obtained bicyclic compounds provide transannular products in a stereospecific fashion. Furthermore, a direct transannular reaction of diallylic amide involving sequential intermolecular-intramolecular reactions has been developed.

Original languageEnglish
Pages (from-to)4926-4929
Number of pages4
JournalOrganic Letters
Issue number18
Publication statusPublished - Sep 16 2011


All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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