TY - JOUR
T1 - Stereoselective total synthesis of zaragozic acid A based on an acetal [1,2] Wittig rearrangement
AU - Tomooka, Katsuhiko
AU - Kikuchi, Makoto
AU - Igawa, Kazunobu
AU - Suzuki, Masaki
AU - Keong, Ping Huai
AU - Nakai, Takeshi
PY - 2000/12/15
Y1 - 2000/12/15
N2 - A simultaneous creation of the C4 and C5 quaternary carbon centers by an acetal [1,2] Wittig rearrangement of O-glycoside 1 derived from L-arabino-γ-lactone is the key feature in the construction of the 2,8-dioxabicyclo[3.2.1]octane core structure of zaragozic acid A (2).
AB - A simultaneous creation of the C4 and C5 quaternary carbon centers by an acetal [1,2] Wittig rearrangement of O-glycoside 1 derived from L-arabino-γ-lactone is the key feature in the construction of the 2,8-dioxabicyclo[3.2.1]octane core structure of zaragozic acid A (2).
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U2 - 10.1002/1521-3773(20001215)39:24<4502::AID-ANIE4502>3.0.CO;2-K
DO - 10.1002/1521-3773(20001215)39:24<4502::AID-ANIE4502>3.0.CO;2-K
M3 - Article
AN - SCOPUS:0034671939
SN - 1433-7851
VL - 39
SP - 4502
EP - 4505
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 24
ER -