Stereospecific polymerization with PMMA binding peptide

Kun Zhang; Yusuke Hosaka; Hisao Matsuno; Takeshi Serizawa

Stereospecific polymerization with PMMA binding peptide

Kun Zhang, Yusuke Hosaka, Hisao Matsuno, Takeshi Serizawa

Research output: Contribution to conference › Paper › peer-review

Abstract

Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)₂, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

Original language	English
Pages	716
Number of pages	1
Publication status	Published - 2006
Externally published	Yes
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: May 24 2006 → May 26 2006

Other

Other	55th SPSJ Annual Meeting
Country/Territory	Japan
City	Nagoya
Period	5/24/06 → 5/26/06

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

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title = "Stereospecific polymerization with PMMA binding peptide",

abstract = "Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.",

author = "Kun Zhang and Yusuke Hosaka and Hisao Matsuno and Takeshi Serizawa",

year = "2006",

language = "English",

pages = "716",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

}

TY - CONF

T1 - Stereospecific polymerization with PMMA binding peptide

AU - Zhang, Kun

AU - Hosaka, Yusuke

AU - Matsuno, Hisao

AU - Serizawa, Takeshi

PY - 2006

Y1 - 2006

N2 - Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

AB - Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

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UR - http://www.scopus.com/inward/citedby.url?scp=33749676649&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33749676649

SP - 716

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Stereospecific polymerization with PMMA binding peptide

Abstract

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All Science Journal Classification (ASJC) codes

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