Structural characterization of molybdenum-dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

Akira Yamamoto, Kazuya Arashiba, Shimpei Naniwa, Kazuo Kato, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi, Hisao Yoshida

Research output: Contribution to journalArticle

Abstract

The structural characterization of a hardly-isolatable molybdenum-dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.

Original languageEnglish
Pages (from-to)12368-12372
Number of pages5
JournalPhysical Chemistry Chemical Physics
Volume22
Issue number22
DOIs
Publication statusPublished - Jun 14 2020

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Structural characterization of molybdenum-dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy'. Together they form a unique fingerprint.

  • Cite this