Structural, optical, and transport properties of α- And β-Ag 3VO 4

V. Cloet, A. Raw, K. R. Poeppelmeier, G. Trimarchi, H. Peng, J. Im, A. J. Freeman, Nicola Helen Perry, T. O. Mason, A. Zakutayev, P. F. Ndione, D. S. Ginley, J. D. Perkins

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

Original languageEnglish
Pages (from-to)3346-3354
Number of pages9
JournalChemistry of Materials
Volume24
Issue number17
DOIs
Publication statusPublished - Sep 11 2012

Fingerprint

Transport properties
Structural properties
Optical properties
Single crystals
Electric properties
Spectroscopy
Optical conductivity
X ray diffraction
Thin films
Pulsed laser deposition
Superconducting transition temperature
Sputtering
Phase transitions
Electric Conductivity

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Cloet, V., Raw, A., Poeppelmeier, K. R., Trimarchi, G., Peng, H., Im, J., ... Perkins, J. D. (2012). Structural, optical, and transport properties of α- And β-Ag 3VO 4 Chemistry of Materials, 24(17), 3346-3354. https://doi.org/10.1021/cm301119c

Structural, optical, and transport properties of α- And β-Ag 3VO 4 . / Cloet, V.; Raw, A.; Poeppelmeier, K. R.; Trimarchi, G.; Peng, H.; Im, J.; Freeman, A. J.; Perry, Nicola Helen; Mason, T. O.; Zakutayev, A.; Ndione, P. F.; Ginley, D. S.; Perkins, J. D.

In: Chemistry of Materials, Vol. 24, No. 17, 11.09.2012, p. 3346-3354.

Research output: Contribution to journalArticle

Cloet, V, Raw, A, Poeppelmeier, KR, Trimarchi, G, Peng, H, Im, J, Freeman, AJ, Perry, NH, Mason, TO, Zakutayev, A, Ndione, PF, Ginley, DS & Perkins, JD 2012, 'Structural, optical, and transport properties of α- And β-Ag 3VO 4 ', Chemistry of Materials, vol. 24, no. 17, pp. 3346-3354. https://doi.org/10.1021/cm301119c
Cloet V, Raw A, Poeppelmeier KR, Trimarchi G, Peng H, Im J et al. Structural, optical, and transport properties of α- And β-Ag 3VO 4 Chemistry of Materials. 2012 Sep 11;24(17):3346-3354. https://doi.org/10.1021/cm301119c
Cloet, V. ; Raw, A. ; Poeppelmeier, K. R. ; Trimarchi, G. ; Peng, H. ; Im, J. ; Freeman, A. J. ; Perry, Nicola Helen ; Mason, T. O. ; Zakutayev, A. ; Ndione, P. F. ; Ginley, D. S. ; Perkins, J. D. / Structural, optical, and transport properties of α- And β-Ag 3VO 4 In: Chemistry of Materials. 2012 ; Vol. 24, No. 17. pp. 3346-3354.
@article{d5d34d5cad2846fe90e3f2cc68c83f2f,
title = "Structural, optical, and transport properties of α- And β-Ag 3VO 4",
abstract = "The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.",
author = "V. Cloet and A. Raw and Poeppelmeier, {K. R.} and G. Trimarchi and H. Peng and J. Im and Freeman, {A. J.} and Perry, {Nicola Helen} and Mason, {T. O.} and A. Zakutayev and Ndione, {P. F.} and Ginley, {D. S.} and Perkins, {J. D.}",
year = "2012",
month = "9",
day = "11",
doi = "10.1021/cm301119c",
language = "English",
volume = "24",
pages = "3346--3354",
journal = "Chemistry of Materials",
issn = "0897-4756",
publisher = "American Chemical Society",
number = "17",

}

TY - JOUR

T1 - Structural, optical, and transport properties of α- And β-Ag 3VO 4

AU - Cloet, V.

AU - Raw, A.

AU - Poeppelmeier, K. R.

AU - Trimarchi, G.

AU - Peng, H.

AU - Im, J.

AU - Freeman, A. J.

AU - Perry, Nicola Helen

AU - Mason, T. O.

AU - Zakutayev, A.

AU - Ndione, P. F.

AU - Ginley, D. S.

AU - Perkins, J. D.

PY - 2012/9/11

Y1 - 2012/9/11

N2 - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

AB - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

UR - http://www.scopus.com/inward/record.url?scp=84866064302&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84866064302&partnerID=8YFLogxK

U2 - 10.1021/cm301119c

DO - 10.1021/cm301119c

M3 - Article

AN - SCOPUS:84866064302

VL - 24

SP - 3346

EP - 3354

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 17

ER -