Abstract
A unique 3d-4f mixed metal trinuclear compound, [Cu2Gd(L)2(NO3)2]NO3 (1; H2L = 2,6-di(acetoacetyl)pyridine), is derived from a 'one-pot' reaction with H2L, Cu(NO3)2 · 3H2O and Gd(NO3)3 · 5H2O. Two L2- providing one central 2,6-diacylpyridine site and two terminal 1,3-diketonate sites hold two CuII ions and GdIII ion and form a linear Cu-Gd-Cu trinuclear core. This compound shows ferromagnetic interaction between CuII and GdIII.
Original language | English |
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Pages (from-to) | 15-18 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 6 |
Issue number | 1 |
DOIs | |
Publication status | Published - Jan 1 2003 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry