TY - JOUR
T1 - Structure and magnetism of a trinuclear CuII-GdIII-CuII complex derived from one-pot reaction with 2,6-di(acetoacetyl)pyridine
AU - Shiga, Takuya
AU - Ohba, Masaaki
AU - Okawa, Hisashi
N1 - Funding Information:
This work was supported by a Grant-in-Aid for COE Research “Design and Control of Advanced Molecular Assembly System (No. 08CE2005)”, a Grant-in-Aid for Scientific Research Program (No. 13640561) from the Ministry of Education, Culture, Sports, Science and Technology and Precursory Research for Embryonic Science and Technology (PRESTO), JST, Japan.
Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2003/1/1
Y1 - 2003/1/1
N2 - A unique 3d-4f mixed metal trinuclear compound, [Cu2Gd(L)2(NO3)2]NO3 (1; H2L = 2,6-di(acetoacetyl)pyridine), is derived from a 'one-pot' reaction with H2L, Cu(NO3)2 · 3H2O and Gd(NO3)3 · 5H2O. Two L2- providing one central 2,6-diacylpyridine site and two terminal 1,3-diketonate sites hold two CuII ions and GdIII ion and form a linear Cu-Gd-Cu trinuclear core. This compound shows ferromagnetic interaction between CuII and GdIII.
AB - A unique 3d-4f mixed metal trinuclear compound, [Cu2Gd(L)2(NO3)2]NO3 (1; H2L = 2,6-di(acetoacetyl)pyridine), is derived from a 'one-pot' reaction with H2L, Cu(NO3)2 · 3H2O and Gd(NO3)3 · 5H2O. Two L2- providing one central 2,6-diacylpyridine site and two terminal 1,3-diketonate sites hold two CuII ions and GdIII ion and form a linear Cu-Gd-Cu trinuclear core. This compound shows ferromagnetic interaction between CuII and GdIII.
UR - http://www.scopus.com/inward/record.url?scp=0037230757&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037230757&partnerID=8YFLogxK
U2 - 10.1016/S1387-7003(02)00674-3
DO - 10.1016/S1387-7003(02)00674-3
M3 - Article
AN - SCOPUS:0037230757
VL - 6
SP - 15
EP - 18
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
IS - 1
ER -