Structure and physical properties of EDT-TTF salts

Tetsuo Kondo; Lyudmila A. Kushch; Hideki Yamochi; Gunzi Saito

Structure and physical properties of EDT-TTF salts

Tetsuo Kondo, Lyudmila A. Kushch, Hideki Yamochi, Gunzi Saito

Research output: Contribution to journal › Conference article › peer-review

Abstract

Charge-transfer salts of EDT-TTF with tetrahedral anions MX₄ (M = Fe, Ga; X = Cl, Br) were prepared. They are isostructural to each other (monoclinic P2₁/m) with the stoichiometry of 2:1. All of them are semiconductors having the conductivity at room temperature of 5 to 9 Scm^-1 and activation energy of 40 to 170 meV. Since the calculated band structure of them indicate that they should be quasi one-dimensional metals, they were discussed from the point of structural deformation and strong electron correlation.

Original language	English
Pages (from-to)	921-926
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	488
Publication status	Published - Dec 1 1997
Externally published	Yes
Event	Proceedings of the 1997 MRS Fall Meeting - Boston, MA, USA Duration: Dec 1 1997 → Dec 4 1997

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

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title = "Structure and physical properties of EDT-TTF salts",

abstract = "Charge-transfer salts of EDT-TTF with tetrahedral anions MX4 (M = Fe, Ga; X = Cl, Br) were prepared. They are isostructural to each other (monoclinic P21/m) with the stoichiometry of 2:1. All of them are semiconductors having the conductivity at room temperature of 5 to 9 Scm-1 and activation energy of 40 to 170 meV. Since the calculated band structure of them indicate that they should be quasi one-dimensional metals, they were discussed from the point of structural deformation and strong electron correlation.",

author = "Tetsuo Kondo and Kushch, {Lyudmila A.} and Hideki Yamochi and Gunzi Saito",

year = "1997",

month = dec,

day = "1",

language = "English",

volume = "488",

pages = "921--926",

journal = "Materials Research Society Symposium - Proceedings",

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publisher = "Materials Research Society",

note = "Proceedings of the 1997 MRS Fall Meeting ; Conference date: 01-12-1997 Through 04-12-1997",

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TY - JOUR

T1 - Structure and physical properties of EDT-TTF salts

AU - Kondo, Tetsuo

AU - Kushch, Lyudmila A.

AU - Yamochi, Hideki

AU - Saito, Gunzi

PY - 1997/12/1

Y1 - 1997/12/1

N2 - Charge-transfer salts of EDT-TTF with tetrahedral anions MX4 (M = Fe, Ga; X = Cl, Br) were prepared. They are isostructural to each other (monoclinic P21/m) with the stoichiometry of 2:1. All of them are semiconductors having the conductivity at room temperature of 5 to 9 Scm-1 and activation energy of 40 to 170 meV. Since the calculated band structure of them indicate that they should be quasi one-dimensional metals, they were discussed from the point of structural deformation and strong electron correlation.

AB - Charge-transfer salts of EDT-TTF with tetrahedral anions MX4 (M = Fe, Ga; X = Cl, Br) were prepared. They are isostructural to each other (monoclinic P21/m) with the stoichiometry of 2:1. All of them are semiconductors having the conductivity at room temperature of 5 to 9 Scm-1 and activation energy of 40 to 170 meV. Since the calculated band structure of them indicate that they should be quasi one-dimensional metals, they were discussed from the point of structural deformation and strong electron correlation.

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M3 - Conference article

AN - SCOPUS:0031368624

SN - 0272-9172

VL - 488

SP - 921

EP - 926

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Proceedings of the 1997 MRS Fall Meeting

Y2 - 1 December 1997 through 4 December 1997

ER -

Structure and physical properties of EDT-TTF salts

Abstract

All Science Journal Classification (ASJC) codes

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