Structures of bimetallic assemblies derived from a macrocyclic dinuclear copper(II) complex and [Cr(ox)3]3- or [Co(CN) 6]3-

Yuji Miyazato, Masaaki Ohba, Hisashi Okawa

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Abstract

A dinuclear copper(II) complex, [Cu2(L)](ClO4) 2, of the macrocyclic ligand (H2L) derived from the [2:2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane, was reacted with [Cr(ox)3]3- and [Co(CN)6]3- to produce [Cu2(L)]3[Cr(ox)3]2 · 6MeOH (1) of a discrete octanuclear structure and [Cu2(L)] 3[Co(CN)6]2 · 6MeOH · 2DMF (2) of a 2-D grid structure, respectively.

Original languageEnglish
Pages (from-to)1646-1648
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume78
Issue number9
DOIs
Publication statusPublished - Sep 15 2005

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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