Studies on the adsorption of organic materials inside thick carbon nanotubes

Masako Yudasaka, Jing Fan, Jin Miyawaki, Sumio Iijima

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

We clarified the adsorption sites inside the single-wall carbon nanohorns (SWNHs), a type of single-wall carbon nanotubes having thick diameters of 2-5 nm, through the thermogravimetric analysis of the desorption of xylene and benzene from SWNHs. The influence of the sizes of holes piercing through the SWNH walls was also examined. Three types of adsorption sites were found inside the SWNH tubes, which were assigned to the tube tips, the sidewalls, and central regions of the hollow spaces. The experimental results also suggested that the adsorbed xylene and benzene were stabilized mainly by weak self-interactions at the central regions and their quick desorption was caused by the weak self-interactions.

Original languageEnglish
Pages (from-to)8909-8913
Number of pages5
JournalJournal of Physical Chemistry B
Volume109
Issue number18
DOIs
Publication statusPublished - May 12 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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