STUDY OF CONDENSATION PROCESS OF ORTHOETHYLSILICATE BY THE METHOD OF TRIMETHYLSILYLATION.

Masaki Makihara, Yoshiro Moriya

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The condensation process of orthoethylsilicate was studied by the trimethylsilylation (TMS) method at various reaction temperatures and at various concentrations of HCl or NH//3. The rate of disappearance and/or appearance of monomer, dimer and cyclic tetramer increased with rising reaction temperature. The molecular weight distribution curves of trimethylsilyl derivatives showed many peaks at the positions corresponding to fixed molecular weights, and the perk positions did not change with reaction temperatures. At both low and high pH ranges, the growth of particles, which were formed by hydrolysis, was observed.

Original languageEnglish
Pages (from-to)328-333
Number of pages6
JournalYogyo Kyokai Shi/Journal of the Ceramic Society of Japan
Volume92
Issue number6
Publication statusPublished - 1984
Externally publishedYes

Fingerprint

Condensation
condensation
molecular weight
Molecular weight distribution
Dimers
Temperature
temperature
hydrolysis
Hydrolysis
monomers
Monomers
Molecular weight
dimers
Derivatives
curves

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

STUDY OF CONDENSATION PROCESS OF ORTHOETHYLSILICATE BY THE METHOD OF TRIMETHYLSILYLATION. / Makihara, Masaki; Moriya, Yoshiro.

In: Yogyo Kyokai Shi/Journal of the Ceramic Society of Japan, Vol. 92, No. 6, 1984, p. 328-333.

Research output: Contribution to journalArticle

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