Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR

Hiroyuki Ishida, Yuko Miwa, Akira Mochizuki, Masaru Tanaka

Research output: Contribution to conferencePaper

Abstract

The states of water in membranes of PMEA and PHEMA were studied with solution 2H-NMR method. The membranes were prepared by spin-coating on PET film. In order to investigate the change in the behavior of water with time after adding of H2O in membranes of PMEA and PHEMA, 2H-NMR measurements were carried out. From the results of the time dependence spectra and spin-lattice relaxation time T1, the followings were concluded. The mobility of water molecule in the PMEA membrane after H2O addition was higher than that in the PHEMA membrane, while exchange rates of the water between inside and outside of the PMEA membrane were slower than those of the PHEMA membrane. The state of water structure in the PMEA membrane is more stable than that in the PHEMA membrane.

Original languageEnglish
Pages4375-4376
Number of pages2
Publication statusPublished - Dec 1 2006
Externally publishedYes
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: Sep 20 2006Sep 22 2006

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period9/20/069/22/06

Fingerprint

PHEMA
Nuclear magnetic resonance
Membranes
Water
Spin-lattice relaxation
Spin coating
Relaxation time

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Ishida, H., Miwa, Y., Mochizuki, A., & Tanaka, M. (2006). Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR. 4375-4376. Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.

Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR. / Ishida, Hiroyuki; Miwa, Yuko; Mochizuki, Akira; Tanaka, Masaru.

2006. 4375-4376 Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.

Research output: Contribution to conferencePaper

Ishida, H, Miwa, Y, Mochizuki, A & Tanaka, M 2006, 'Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR', Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan, 9/20/06 - 9/22/06 pp. 4375-4376.
Ishida H, Miwa Y, Mochizuki A, Tanaka M. Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR. 2006. Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.
Ishida, Hiroyuki ; Miwa, Yuko ; Mochizuki, Akira ; Tanaka, Masaru. / Study on structure of water in membranes of PMEA and PHEMA by 2H-NMR. Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.2 p.
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