Substitution effect of rare earth on hydrogenation for AB5-type alloys

Daisuke Endo, Etsuo Akiba

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Substitution effects of rare earth elements for hydrogenation of MmNi 3.55Co0.75Al0.30Mn0.40 AB 5-type alloys were investigated, where Mm consisted of La-Pr-Nd-M (M: Ce, Y, Gd, Tm and Lu), and the amount of La and M was adjusted to keep the lattice volume identical which leads to a similar equilibrium hydrogen pressure. The above alloys showed two-phase reaction during hydrogenation, and both the phases had the orthorhombic lattice with a space group of Cmmm after activation. The Ce containing alloy showed a higher equilibrium hydrogen pressure (0.12 MPa) than the others (0.07-0.10 MPa) at 298 K. In addition, this alloy showed the largest lattice volume expansion among the alloys investigated. However, lattice strain of the hydride phases calculated from line broadening in X-ray diffraction peaks showed to be less than 0.9% for all the alloys investigated.

Original languageEnglish
Pages (from-to)1914-1917
Number of pages4
JournalMaterials Transactions
Volume47
Issue number8
DOIs
Publication statusPublished - Aug 1 2006

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Rare earths
Hydrogenation
hydrogenation
Substitution reactions
rare earth elements
substitutes
Hydrogen
hydrogen
Rare earth elements
Hydrides
hydrides
Chemical activation
activation
X ray diffraction
expansion
diffraction
x rays

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Substitution effect of rare earth on hydrogenation for AB5-type alloys. / Endo, Daisuke; Akiba, Etsuo.

In: Materials Transactions, Vol. 47, No. 8, 01.08.2006, p. 1914-1917.

Research output: Contribution to journalArticle

Endo, Daisuke ; Akiba, Etsuo. / Substitution effect of rare earth on hydrogenation for AB5-type alloys. In: Materials Transactions. 2006 ; Vol. 47, No. 8. pp. 1914-1917.
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