Substitution of oh with nh2 calix[4]arenes: An approach to the synthesis of aminocalixarenes

Fumio Ohseto; Hiroto Murakami; Koji Araki; Seiji Shinkai

doi:10.1016/S0040-4039(00)91900-2

Substitution of oh with nh₂ calix[4]arenes: An approach to the synthesis of aminocalixarenes

Fumio Ohseto, Hiroto Murakami, Koji Araki, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

From p-t-butylcalix[4]arene bis(diethylphosphate) ester(1), monodehydroxymonoamino-p-t-butylcalix[4]arene (3) and diamino-p-t-butyl-calix[4]arene (4) were synthesized in liquid ammonia-co-solvent in the presence of KNH₂. This is the first successful example for the substitution of the OH group with the NH₂ group.

Original language	English
Pages (from-to)	1217-1220
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)91900-2
Publication status	Published - Feb 25 1992

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)91900-2

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abstract = "From p-t-butylcalix[4]arene bis(diethylphosphate) ester(1), monodehydroxymonoamino-p-t-butylcalix[4]arene (3) and diamino-p-t-butyl-calix[4]arene (4) were synthesized in liquid ammonia-co-solvent in the presence of KNH2. This is the first successful example for the substitution of the OH group with the NH2 group.",

author = "Fumio Ohseto and Hiroto Murakami and Koji Araki and Seiji Shinkai",

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AU - Ohseto, Fumio

AU - Murakami, Hiroto

AU - Araki, Koji

AU - Shinkai, Seiji

PY - 1992/2/25

Y1 - 1992/2/25

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AB - From p-t-butylcalix[4]arene bis(diethylphosphate) ester(1), monodehydroxymonoamino-p-t-butylcalix[4]arene (3) and diamino-p-t-butyl-calix[4]arene (4) were synthesized in liquid ammonia-co-solvent in the presence of KNH2. This is the first successful example for the substitution of the OH group with the NH2 group.

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Substitution of oh with nh₂ calix[4]arenes: An approach to the synthesis of aminocalixarenes

Abstract

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