13C and27Al NMR study on the interaction in acidic aqueous solution between aluminium ion and tiron, salicylic acid and phthalic acid: As model compounds with functional groups of fulvic acid

Takushi Yokoyama, Hikaru Abe, Tsutomu Kurisaki, Hisanobu Wakita

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Abstract

The interaction between aluminium ion and tiron (Tr), salicylic acid (Sa), and phthalic acid (Pa) as model compounds for functional groups of fulvic acid in aqueous solution of pH 3 was investigated by the 13C and 27Al NMR method. In the 27Al NMR spectra peaks due to 1:1 aluminium-ligand complexes were observed at 15.7, 2.6 and -3.5 ppm. No peak due to a 1:2 complex was observed. By comparing the 13C NMR chemical shifts between free ligands and coordinated ligands, it was evidenced that the three ligands act as bidentate ligands for aluminium ions at pH 3. The binding constants of these complexes at pH 3 were estimated to be 6× 102 (Tr), 3×102 (Sa) and 3×10 (Pa) mol-1 · dm3. These findings show that the stability of these chelate complexes depends on the chelate effect (stability: five>six≫seven membered ring).

Original languageEnglish
Pages (from-to)425-428
Number of pages4
JournalAnalytical Sciences
Volume13
Issue numberSUPPL.
Publication statusPublished - Dec 1 1997

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1,2-Dihydroxybenzene-3,5-Disulfonic Acid Disodium Salt
Salicylic Acid
Aluminum
Functional groups
Nuclear magnetic resonance
Ions
Ligands
Chemical shift
fulvic acid
phthalic acid

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

13C and27Al NMR study on the interaction in acidic aqueous solution between aluminium ion and tiron, salicylic acid and phthalic acid : As model compounds with functional groups of fulvic acid. / Yokoyama, Takushi; Abe, Hikaru; Kurisaki, Tsutomu; Wakita, Hisanobu.

In: Analytical Sciences, Vol. 13, No. SUPPL., 01.12.1997, p. 425-428.

Research output: Contribution to journalArticle

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abstract = "The interaction between aluminium ion and tiron (Tr), salicylic acid (Sa), and phthalic acid (Pa) as model compounds for functional groups of fulvic acid in aqueous solution of pH 3 was investigated by the 13C and 27Al NMR method. In the 27Al NMR spectra peaks due to 1:1 aluminium-ligand complexes were observed at 15.7, 2.6 and -3.5 ppm. No peak due to a 1:2 complex was observed. By comparing the 13C NMR chemical shifts between free ligands and coordinated ligands, it was evidenced that the three ligands act as bidentate ligands for aluminium ions at pH 3. The binding constants of these complexes at pH 3 were estimated to be 6× 102 (Tr), 3×102 (Sa) and 3×10 (Pa) mol-1 · dm3. These findings show that the stability of these chelate complexes depends on the chelate effect (stability: five>six≫seven membered ring).",
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