Abstract
2 H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak
| Original language | English |
|---|---|
| Pages (from-to) | 561-566 |
| Number of pages | 6 |
| Journal | Clays and Clay Minerals |
| Volume | 42 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Jan 1 1994 |
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All Science Journal Classification (ASJC) codes
- Water Science and Technology
- Soil Science
- Geochemistry and Petrology
- Earth and Planetary Sciences (miscellaneous)
Cite this
2 H NMR study of hydrogen bonding in deuterated kaolinite . / Hayashi, Shigenobu; Akiba, Etsuo; Miyawaki, Ritsuro; Tomura, Shinji.
In: Clays and Clay Minerals, Vol. 42, No. 5, 01.01.1994, p. 561-566.Research output: Contribution to journal › Article
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TY - JOUR
T1 - 2 H NMR study of hydrogen bonding in deuterated kaolinite
AU - Hayashi, Shigenobu
AU - Akiba, Etsuo
AU - Miyawaki, Ritsuro
AU - Tomura, Shinji
PY - 1994/1/1
Y1 - 1994/1/1
N2 - 2 H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak
AB - 2 H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak
UR - http://www.scopus.com/inward/record.url?scp=0028592288&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028592288&partnerID=8YFLogxK
U2 - 10.1346/CCMN.1994.0420507
DO - 10.1346/CCMN.1994.0420507
M3 - Article
VL - 42
SP - 561
EP - 566
JO - Clays and Clay Minerals
JF - Clays and Clay Minerals
SN - 0009-8604
IS - 5
ER -