2H NMR study of hydrogen bonding in deuterated kaolinite

Shigenobu Hayashi; Etsuo Akiba; Ritsuro Miyawaki; Shinji Tomura

doi:10.1346/CCMN.1994.0420507

²H NMR study of hydrogen bonding in deuterated kaolinite

Shigenobu Hayashi, Etsuo Akiba, Ritsuro Miyawaki, Shinji Tomura

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

²H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

Original language	English
Pages (from-to)	561-566
Number of pages	6
Journal	Clays and Clay Minerals
Volume	42
Issue number	5
DOIs	https://doi.org/10.1346/CCMN.1994.0420507
Publication status	Published - Oct 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Water Science and Technology
Soil Science
Geochemistry and Petrology
Earth and Planetary Sciences (miscellaneous)

Access to Document

10.1346/CCMN.1994.0420507

Cite this

@article{789273a6422848c2a8bbd45a003c2cd7,

title = "2H NMR study of hydrogen bonding in deuterated kaolinite",

abstract = "2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak",

author = "Shigenobu Hayashi and Etsuo Akiba and Ritsuro Miyawaki and Shinji Tomura",

year = "1994",

month = oct,

doi = "10.1346/CCMN.1994.0420507",

language = "English",

volume = "42",

pages = "561--566",

journal = "Clays and Clay Minerals",

issn = "0009-8604",

publisher = "Clay Minerals Society",

number = "5",

}

TY - JOUR

T1 - 2H NMR study of hydrogen bonding in deuterated kaolinite

AU - Hayashi, Shigenobu

AU - Akiba, Etsuo

AU - Miyawaki, Ritsuro

AU - Tomura, Shinji

PY - 1994/10

Y1 - 1994/10

N2 - 2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

AB - 2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

UR - http://www.scopus.com/inward/record.url?scp=0028592288&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0028592288&partnerID=8YFLogxK

U2 - 10.1346/CCMN.1994.0420507

DO - 10.1346/CCMN.1994.0420507

M3 - Article

AN - SCOPUS:0028592288

VL - 42

SP - 561

EP - 566

JO - Clays and Clay Minerals

JF - Clays and Clay Minerals

SN - 0009-8604

IS - 5

ER -

²H NMR study of hydrogen bonding in deuterated kaolinite

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this