2 H NMR study of hydrogen bonding in deuterated kaolinite

Shigenobu Hayashi, Etsuo Akiba, Ritsuro Miyawaki, Shinji Tomura

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

2 H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are almost fixed spatially, and undergo a wobbling motion with increasing temperature. The quadrupole coupling constant is 273 ± 3 kHz at 150 K, which indicates that interlayer hydrogen bonding is relatively weak

Original languageEnglish
Pages (from-to)561-566
Number of pages6
JournalClays and Clay Minerals
Volume42
Issue number5
DOIs
Publication statusPublished - Jan 1 1994

Fingerprint

Kaolin
hydrogen bonding
kaolinite
nuclear magnetic resonance
Hydrogen bonds
Nuclear magnetic resonance
hydrogen
Hydroxyl Radical
asymmetry
temperature
Temperature

All Science Journal Classification (ASJC) codes

  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth and Planetary Sciences (miscellaneous)

Cite this

2 H NMR study of hydrogen bonding in deuterated kaolinite . / Hayashi, Shigenobu; Akiba, Etsuo; Miyawaki, Ritsuro; Tomura, Shinji.

In: Clays and Clay Minerals, Vol. 42, No. 5, 01.01.1994, p. 561-566.

Research output: Contribution to journalArticle

Hayashi, S, Akiba, E, Miyawaki, R & Tomura, S 1994, '2 H NMR study of hydrogen bonding in deuterated kaolinite ', Clays and Clay Minerals, vol. 42, no. 5, pp. 561-566. https://doi.org/10.1346/CCMN.1994.0420507
Hayashi, Shigenobu ; Akiba, Etsuo ; Miyawaki, Ritsuro ; Tomura, Shinji. / 2 H NMR study of hydrogen bonding in deuterated kaolinite In: Clays and Clay Minerals. 1994 ; Vol. 42, No. 5. pp. 561-566.
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