Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

Ryohei Akiyoshi, Keita Kuroiwa, Saliu Alao Amolegbe, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.

Original languageEnglish
Pages (from-to)4685-4687
Number of pages3
JournalChemical Communications
Volume53
Issue number34
DOIs
Publication statusPublished - Jan 1 2017

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Cobalt compounds
Cobalt
Magnetic susceptibility
Anions
Negative ions
Wire
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Akiyoshi, R., Kuroiwa, K., Alao Amolegbe, S., Nakaya, M., Ohtani, R., Nakamura, M., ... Hayami, S. (2017). Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds. Chemical Communications, 53(34), 4685-4687. https://doi.org/10.1039/c7cc01501a

Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds. / Akiyoshi, Ryohei; Kuroiwa, Keita; Alao Amolegbe, Saliu; Nakaya, Manabu; Ohtani, Ryo; Nakamura, Masaaki; Lindoy, Leonard F.; Hayami, Shinya.

In: Chemical Communications, Vol. 53, No. 34, 01.01.2017, p. 4685-4687.

Research output: Contribution to journalArticle

Akiyoshi, R, Kuroiwa, K, Alao Amolegbe, S, Nakaya, M, Ohtani, R, Nakamura, M, Lindoy, LF & Hayami, S 2017, 'Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds', Chemical Communications, vol. 53, no. 34, pp. 4685-4687. https://doi.org/10.1039/c7cc01501a
Akiyoshi, Ryohei ; Kuroiwa, Keita ; Alao Amolegbe, Saliu ; Nakaya, Manabu ; Ohtani, Ryo ; Nakamura, Masaaki ; Lindoy, Leonard F. ; Hayami, Shinya. / Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds. In: Chemical Communications. 2017 ; Vol. 53, No. 34. pp. 4685-4687.
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