Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films

Jingxin Zhou, Tifeng Jiao, Adan Li, Yuanyuan Xing

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Functional luminol derivative with cholesteryl substituted group has been designed and synthesized from the reaction of the corresponding precursor cholesteryl chloroformate with luminol. This compound can be spread on water surface to form stable monolayer. It has been found that UV and IR spectra confirmed the characteristic aromatic segment, imide group and cholesteryl substituted group. In addition, the CD spectra also showed positive CD signals, which may be attributed to the chiral cholesteryl substituted groups. AFM investigation indicated some aggregated domains with the averaged height about 3.6 ± 0.2 nm appeared. This suggested an organized structure of double molecules may be fabricated in the transferred LB films. The present results have demonstrated that the interfacial properties of luminol derivative can be modified by changing proper substituted groups of luminol, which show potential application in functional material fields such as ECL sensor.

Original languageEnglish
Title of host publicationFrontiers of Materials, Chemical and Metallurgical Technologies
Pages176-179
Number of pages4
Edition1
DOIs
Publication statusPublished - Nov 28 2012
Event2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012 - KunMing, China
Duration: Oct 12 2012Oct 13 2012

Publication series

NameAdvanced Materials Research
Number1
Volume581-582
ISSN (Print)1022-6680

Other

Other2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012
CountryChina
CityKunMing
Period10/12/1210/13/12

Fingerprint

Derivatives
Emitter coupled logic circuits
Functional materials
Langmuir Blodgett films
Monolayers
Molecules
Sensors
Water

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Zhou, J., Jiao, T., Li, A., & Xing, Y. (2012). Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. In Frontiers of Materials, Chemical and Metallurgical Technologies (1 ed., pp. 176-179). (Advanced Materials Research; Vol. 581-582, No. 1). https://doi.org/10.4028/www.scientific.net/AMR.581-582.176

Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. / Zhou, Jingxin; Jiao, Tifeng; Li, Adan; Xing, Yuanyuan.

Frontiers of Materials, Chemical and Metallurgical Technologies. 1. ed. 2012. p. 176-179 (Advanced Materials Research; Vol. 581-582, No. 1).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Zhou, J, Jiao, T, Li, A & Xing, Y 2012, Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. in Frontiers of Materials, Chemical and Metallurgical Technologies. 1 edn, Advanced Materials Research, no. 1, vol. 581-582, pp. 176-179, 2012 International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials, CMMM 2012, KunMing, China, 10/12/12. https://doi.org/10.4028/www.scientific.net/AMR.581-582.176
Zhou J, Jiao T, Li A, Xing Y. Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. In Frontiers of Materials, Chemical and Metallurgical Technologies. 1 ed. 2012. p. 176-179. (Advanced Materials Research; 1). https://doi.org/10.4028/www.scientific.net/AMR.581-582.176
Zhou, Jingxin ; Jiao, Tifeng ; Li, Adan ; Xing, Yuanyuan. / Supramolecular assembly of functional cholesteryl substituted luminol derivative in organized molecular films. Frontiers of Materials, Chemical and Metallurgical Technologies. 1. ed. 2012. pp. 176-179 (Advanced Materials Research; 1).
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