Supramolecular macrocycles self-assembled by phenanthroline-Cu(I) and sugar-boronic acid interactions

Masashi Yamamoto; Masayuki Takeuchi; Seiji Shinkai

doi:10.1016/S0040-4039(00)00370-1

Supramolecular macrocycles self-assembled by phenanthroline-Cu(I) and sugar-boronic acid interactions

Masashi Yamamoto, Masayuki Takeuchi, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Two kinds of ligand which have two phenanthroline groups linked by a C₂-symmetrical chiral tetrol were synthesized by a boronic acid-diol interaction. It was shown that these ligands form unique dinuclear chiral macrocycles by a Cu(I)-phenanthroline interaction. The results indicate that a novel supramolecular system can be exploited by combination of the Cu(I)- phenanthroline interaction with the boronic acid-diol interaction.

Original language	English
Pages (from-to)	3137-3140
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4039(00)00370-1
Publication status	Published - Apr 22 2000

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All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Cite this

Yamamoto, M., Takeuchi, M., & Shinkai, S. (2000). Supramolecular macrocycles self-assembled by phenanthroline-Cu(I) and sugar-boronic acid interactions. Tetrahedron Letters, 41(17), 3137-3140. https://doi.org/10.1016/S0040-4039(00)00370-1

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abstract = "Two kinds of ligand which have two phenanthroline groups linked by a C2-symmetrical chiral tetrol were synthesized by a boronic acid-diol interaction. It was shown that these ligands form unique dinuclear chiral macrocycles by a Cu(I)-phenanthroline interaction. The results indicate that a novel supramolecular system can be exploited by combination of the Cu(I)- phenanthroline interaction with the boronic acid-diol interaction.",

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AB - Two kinds of ligand which have two phenanthroline groups linked by a C2-symmetrical chiral tetrol were synthesized by a boronic acid-diol interaction. It was shown that these ligands form unique dinuclear chiral macrocycles by a Cu(I)-phenanthroline interaction. The results indicate that a novel supramolecular system can be exploited by combination of the Cu(I)- phenanthroline interaction with the boronic acid-diol interaction.

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Access to Document

10.1016/S0040-4039(00)00370-1