Surface modification of non-woven electrospun fine fiber mats through surface-initiated atom transfer radical polymerization

Yuji Higaki, Takahiro Yano, Di Tao, Hirofumi Kabayama, Atsushi Takahara

Research output: Contribution to journalArticle

Abstract

Electrospun fine fibers were surface-modified by surface-initiated atom transfer radical polymerization (SI-ATRP) to reform their surface character without sacrificing their bulk properties. Electrospun fibers of two types of polymers, poly(methyl methacrylate)-based copolymers and semicrystalline poly(butylene terephthalate), that have ATRP initiating units attached to them were modified by poly(sulfobetaine) brushes or fluorinated polymer brushes. The fluorinated polymer brushes make the electrospun fiber mat super-hydrophobic, whereas the poly(sulfobetaine) brushes make the electrospun fiber super-hydrophilic. These mats can be used for water/oil separation and exhibit non-fouling properties. The semi-crystalline polyester fibers keep these properties even at elevated temperatures.

Original languageEnglish
Pages (from-to)225-232
Number of pages8
JournalKobunshi Ronbunshu
Volume73
Issue number3
DOIs
Publication statusPublished - Jan 1 2016

Fingerprint

Atom transfer radical polymerization
polymerization
Surface treatment
Brushes
Fluorocarbon Polymers
Fibers
polymer
Polymers
Polyesters
Polymethyl Methacrylate
Polymethyl methacrylates
Oils
Copolymers
fibre
Crystalline materials
Water
oil
temperature
water
Temperature

All Science Journal Classification (ASJC) codes

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Environmental Science(all)
  • Polymers and Plastics

Cite this

Surface modification of non-woven electrospun fine fiber mats through surface-initiated atom transfer radical polymerization. / Higaki, Yuji; Yano, Takahiro; Tao, Di; Kabayama, Hirofumi; Takahara, Atsushi.

In: Kobunshi Ronbunshu, Vol. 73, No. 3, 01.01.2016, p. 225-232.

Research output: Contribution to journalArticle

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