Surface oxygen atom as a cooperative ligand in Pd nanoparticle catalysis for selective hydration of nitriles to amides in water: Experimental and theoretical studies

Ken Ichi Shimizu, Takahiro Kubo, Atsushi Satsuma, Takashi Kamachi, Kazunari Yoshizawa

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

On the basis of an insight in surface science that Pd surfaces partially covered with oxygen adatoms (Oad) show higher reactivity for water dissociation than clean Pd surfaces, we studied the effect of Oad on the activity of carbon-supported palladium metal nanoparticle catalysts (Pd/C) for the selective hydration of nitriles to amides in water. A series of Pd/C with the same Pd loading (5 wt %) and a similar particle size (5.3-6.5 nm) but with different surface coverage of Oad were prepared and characterized by various spectroscopic methods. The freshly H 2-reduced Pd/C shows no catalytic activity for hydration of acetonitrile, indicating that clean Pd metal surfaces are inactive. Air exposure of this catalyst under ambient conditions results in the formation of Pd metal NPs partially covered with Oad, which act as effective and recyclable heterogeneous catalysts for selective hydration of various nitriles to the corresponding amides. Theoretical studies based on density functional theory calculations clarified a cooperative mechanism between metallic Pd and O ad, in which Oad as a Brønsted base site plays an important role in the dissociation of water via hydrogen bonding, and the mechanism is verified by kinetic results (activation energy, H 2O/D2O kinetic isotope effect, Hammett slope). The mechanistic finding demonstrates a new design strategy of metal nanoparticle catalysts based on a molecular-level understanding of catalysis on oxygen-adsorbed metal surfaces.

Original languageEnglish
Pages (from-to)2467-2474
Number of pages8
JournalACS Catalysis
Volume2
Issue number12
DOIs
Publication statusPublished - Dec 7 2012

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Nitriles
Amides
Adatoms
Hydration
Catalysis
Ligands
Oxygen
Nanoparticles
Atoms
Water
Catalysts
Metal nanoparticles
Metals
Kinetics
Palladium
Acetonitrile
Isotopes
Density functional theory
Catalyst activity
Hydrogen bonds

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Surface oxygen atom as a cooperative ligand in Pd nanoparticle catalysis for selective hydration of nitriles to amides in water : Experimental and theoretical studies. / Shimizu, Ken Ichi; Kubo, Takahiro; Satsuma, Atsushi; Kamachi, Takashi; Yoshizawa, Kazunari.

In: ACS Catalysis, Vol. 2, No. 12, 07.12.2012, p. 2467-2474.

Research output: Contribution to journalArticle

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