Suzuki-miyaura cross-coupling of benzylic carbonates with arylboronic acids

Ryoichi Kuwano; Masashi Yokogi

doi:10.1021/ol050078q

Suzuki-miyaura cross-coupling of benzylic carbonates with arylboronic acids

Ryoichi Kuwano, Masashi Yokogi

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

(Chemical Equation Presented) The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(n³-C ₃H₅)Cl]₂ and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.

Original language	English
Pages (from-to)	945-947
Number of pages	3
Journal	Organic Letters
Volume	7
Issue number	5
DOIs	https://doi.org/10.1021/ol050078q
Publication status	Published - Mar 3 2005

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol050078q

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abstract = "(Chemical Equation Presented) The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(n3-C 3H5)Cl]2 and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.",

author = "Ryoichi Kuwano and Masashi Yokogi",

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doi = "10.1021/ol050078q",

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AU - Yokogi, Masashi

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N2 - (Chemical Equation Presented) The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(n3-C 3H5)Cl]2 and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.

AB - (Chemical Equation Presented) The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(n3-C 3H5)Cl]2 and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.

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Suzuki-miyaura cross-coupling of benzylic carbonates with arylboronic acids

Abstract

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