Synergistic effect of water-soluble species and relative humidity on morphological changes in aerosol particles in the Beijing megacity during severe pollution episodes

Xiaole Pan, Baozhu Ge, Zhe Wang, Yu Tian, Hang Liu, Lianfang Wei, Siyao Yue, Itsushi Uno, Hiroshi Kobayashi, Tomoaki Nishizawa, Atsushi Shimizu, Pingqing Fu, Zifa Wang

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9 Citations (Scopus)

Abstract

Depolarization ratio (δ) of backscattered light is an applicable parameter for distinguishing the sphericity of particles in real time, which has been widely adopted by groundbased lidar observation systems. In this study, δ values of particles and chemical compositions in both PM2:5 (aerodynamic diameter less than 2.5 μm) and PM10 (aerodynamic diameter less than 10 μm) were concurrently measured on the basis of a bench-top optical particle counter with a polarization detection module (POPC) and a continuous dichotomous aerosol chemical speciation analyzer (ACSA-14) from November 2016 to February 2017 at an urban site in Beijing megacity. In general, measured δ values depended on both size and sphericity of the particles. During the observation period, mass concentrations of NO-3 in PM 2.5 (fNO 3 ) were about an order of magnitude higher than that in PM 2.5-10 (cNO 3 ) with a mean fNO 3 =cNO 3 ratio of 14±10. A relatively low fNO 3 =cNO 3 ratio (∼ 5) was also observed under higher relative humidity conditions, mostly due to heterogeneous processes and particles in the coarse mode. We found that δ values of ambient particles in both PM 2.5 and PM 2.5-10 obviously decreased as mass concentration of water-soluble species increased at unfavorable meteorological conditions. This indicated that the morphology of particles was changed as a result of water-absorbing processes. The particles with optical size (Dp) of DpD5 μm were used to represent mineral dust particles, and its δ values (δDpD5) decreased by 50% as the mass fraction of cNO 3 increased from 2% to 8% and ambient relative humidity increased up to 80 %, suggesting that mineral dust particles were likely to be spherical during humid pollution episodes. During the observation, relative humidity inside the POPC measuring chamber was stable at 34±2 %, lower than the ambient condition. Its influence on the morphology was estimated to be limited and did not change our major conclusion. This study highlights the evident alteration of non-sphericity of mineral dust particles during their transport owing to a synergistic effect of both pollutant coatings and hygroscopic processes, which plays an important role in the evaluation of its environmental effect.

Original languageEnglish
Pages (from-to)219-232
Number of pages14
JournalAtmospheric Chemistry and Physics
Volume19
Issue number1
DOIs
Publication statusPublished - Jan 7 2019

All Science Journal Classification (ASJC) codes

  • Atmospheric Science

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