Syntheses of metal-organic frameworks with protected phosphonate ligands

Teppei Yamada, Hiroshi Kitagawa

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Protected phosphonate groups were embedded onto isophthalic acid and reacted with zinc ion to synthesize metal-organic frameworks (MOFs). Single-crystal X-ray diffraction measurement revealed the crystal structures of obtained MOFs under various temperatures and solvent conditions. The isopropyl groups were left protected when the complexation reaction was executed at 60 °C, while they were partially deprotected in the sample prepared at 120 °C. When the reaction was carried out at 180 °C, the isopropyl groups were totally deprotected. This result provides us with information on the deprotection reaction in a post-synthetic method for constructing MOFs.

Original languageEnglish
Pages (from-to)4148-4152
Number of pages5
JournalCrystEngComm
Volume14
Issue number12
DOIs
Publication statusPublished - Jun 21 2012
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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