Syntheses of self-assembly polymer complexes by complexation

Yuhki Ohtsuka, Masayoshi Higuchi, Ryo Shomura, Akari Hayashi, Dirk G. Kurth

Research output: Contribution to conferencePaperpeer-review

Abstract

Organic-metallic hybrid materials have received much attention as functional nanodevices having novel magnetic, spectroscopic and electrochemical properties. In our group, metallosupramolecular coordination polymers were developed as functional modular elements. Based on metal ion-induced self-assembly between bis(terpyridyl)benzene and transition metal (Fe(II)), water and alcohol-soluble polymers were formed. They further made complexes with negatively charged phosphates, and the resulted complexes were soluble in organic solvent and formed liquid crystalline phase. The organic-metallic hybrid polymers were researched on the spectroscopic and electrochemical properties in detail. In addition, we would like to describe the preparation of novel bis(terpyridyl)benzene derivatives and the properties of new complexes.

Original languageEnglish
Pages3900-3901
Number of pages2
Publication statusPublished - Dec 1 2005
Externally publishedYes
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: Sept 20 2005Sept 22 2005

Other

Other54th SPSJ Symposium on Macromolecules
Country/TerritoryJapan
CityYamagata
Period9/20/059/22/05

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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