Syntheses of zinc oxide and zinc hydroxide single nanosheets

Ozge Altuntasoglu; Yuki Matsuda; Shintaro Ida; Yasumichi Matsumoto

doi:10.1021/cm100152q

Syntheses of zinc oxide and zinc hydroxide single nanosheets

Ozge Altuntasoglu, Yuki Matsuda, Shintaro Ida, Yasumichi Matsumoto

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

In this study, we present the preparation of zinc oxide (ZnO) and zinc hydroxide (Zn(OH)₂) single nanosheets for the first time. ZnO nanosheet was prepared by delamination of layered ZnO film intercalated with the dodecyl sulfate (DS^-) ion which was synthesized by cathodic electrodeposition process. In this case, the addition of La³⁺ ion into the electrolyte was very critical for the further delamination process. On the other hand, Zn(OH)₂ nanosheet was prepared by delamination of layered Zn(OH)₂ intercalated with the DS^- ion that was prepared by a soft solution process using hexamethylenetetramine (HMT). The thicknesses of the ZnO and Zn(OH)₂ nanosheets were about 0.7 and 1.0 nm, respectively. The structures of the nanosheets were discussed with the results of transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images.

Original language	English
Pages (from-to)	3158-3164
Number of pages	7
Journal	Chemistry of Materials
Volume	22
Issue number	10
DOIs	https://doi.org/10.1021/cm100152q
Publication status	Published - May 25 2010

All Science Journal Classification (ASJC) codes

Materials Chemistry
Chemical Engineering(all)
Chemistry(all)

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10.1021/cm100152q

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title = "Syntheses of zinc oxide and zinc hydroxide single nanosheets",

abstract = "In this study, we present the preparation of zinc oxide (ZnO) and zinc hydroxide (Zn(OH)2) single nanosheets for the first time. ZnO nanosheet was prepared by delamination of layered ZnO film intercalated with the dodecyl sulfate (DS-) ion which was synthesized by cathodic electrodeposition process. In this case, the addition of La3+ ion into the electrolyte was very critical for the further delamination process. On the other hand, Zn(OH)2 nanosheet was prepared by delamination of layered Zn(OH)2 intercalated with the DS- ion that was prepared by a soft solution process using hexamethylenetetramine (HMT). The thicknesses of the ZnO and Zn(OH)2 nanosheets were about 0.7 and 1.0 nm, respectively. The structures of the nanosheets were discussed with the results of transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images.",

author = "Ozge Altuntasoglu and Yuki Matsuda and Shintaro Ida and Yasumichi Matsumoto",

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T1 - Syntheses of zinc oxide and zinc hydroxide single nanosheets

AU - Altuntasoglu, Ozge

AU - Matsuda, Yuki

AU - Ida, Shintaro

AU - Matsumoto, Yasumichi

PY - 2010/5/25

Y1 - 2010/5/25

N2 - In this study, we present the preparation of zinc oxide (ZnO) and zinc hydroxide (Zn(OH)2) single nanosheets for the first time. ZnO nanosheet was prepared by delamination of layered ZnO film intercalated with the dodecyl sulfate (DS-) ion which was synthesized by cathodic electrodeposition process. In this case, the addition of La3+ ion into the electrolyte was very critical for the further delamination process. On the other hand, Zn(OH)2 nanosheet was prepared by delamination of layered Zn(OH)2 intercalated with the DS- ion that was prepared by a soft solution process using hexamethylenetetramine (HMT). The thicknesses of the ZnO and Zn(OH)2 nanosheets were about 0.7 and 1.0 nm, respectively. The structures of the nanosheets were discussed with the results of transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images.

AB - In this study, we present the preparation of zinc oxide (ZnO) and zinc hydroxide (Zn(OH)2) single nanosheets for the first time. ZnO nanosheet was prepared by delamination of layered ZnO film intercalated with the dodecyl sulfate (DS-) ion which was synthesized by cathodic electrodeposition process. In this case, the addition of La3+ ion into the electrolyte was very critical for the further delamination process. On the other hand, Zn(OH)2 nanosheet was prepared by delamination of layered Zn(OH)2 intercalated with the DS- ion that was prepared by a soft solution process using hexamethylenetetramine (HMT). The thicknesses of the ZnO and Zn(OH)2 nanosheets were about 0.7 and 1.0 nm, respectively. The structures of the nanosheets were discussed with the results of transmission electron microscopy (TEM) and selected area electron diffraction (SAED) images.

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Syntheses of zinc oxide and zinc hydroxide single nanosheets

Abstract

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