Syntheses, structures, and crystal packing of n-confused 5,20-diphenylporphyrin and Ag(III) complex

Hiroyuki Furuta, Tatsuki Morimoto, Atsuhiro Osuka

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

(Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å distance in the crystal.

Original languageEnglish
Pages (from-to)1427-1430
Number of pages4
JournalOrganic Letters
Volume5
Issue number9
DOIs
Publication statusPublished - May 1 2003

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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