Abstract
(Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å distance in the crystal.
| Original language | English |
|---|---|
| Pages (from-to) | 1427-1430 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 5 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - May 1 2003 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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Furuta, H., Morimoto, T., & Osuka, A. (2003). Syntheses, structures, and crystal packing of n-confused 5,20-diphenylporphyrin and Ag(III) complex. Organic Letters, 5(9), 1427-1430. https://doi.org/10.1021/ol034172n