Syntheses, structures, and crystal packing of n-confused 5,20-diphenylporphyrin and Ag(III) complex

Hiroyuki Furuta; Tatsuki Morimoto; Atsuhiro Osuka

doi:10.1021/ol034172n

Syntheses, structures, and crystal packing of n-confused 5,20-diphenylporphyrin and Ag(III) complex

Hiroyuki Furuta, Tatsuki Morimoto, Atsuhiro Osuka

Applied Fine Chemistry

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

(Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å distance in the crystal.

Original language	English
Pages (from-to)	1427-1430
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	9
DOIs	https://doi.org/10.1021/ol034172n
Publication status	Published - May 1 2003

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Syntheses, structures, and crystal packing of n-confused 5,20-diphenylporphyrin and Ag(III) complex",

abstract = "(Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 {\AA} distance in the crystal.",

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AU - Furuta, Hiroyuki

AU - Morimoto, Tatsuki

AU - Osuka, Atsuhiro

PY - 2003/5/1

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N2 - (Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å distance in the crystal.

AB - (Matrix presented) β-Unsubstituted meso partially free N-confused porphyrin, N-confused 5,20-diphenylporphyrin (NCDPP, 3), was synthesized in 7% yield by [3 + 1] condensation reaction followed by oxidation. The structures of the free base and its Ag(III) complex were elucidated by the single-crystal X-ray analyses. The Ag(III) complex was more planar than the free base and formed columnar structures stacking to each other with a 3.3 Å distance in the crystal.

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