Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand

Motoki Toganoh, Yutaka Matsuo, Eiichi Nakamura

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.

Original languageEnglish
Pages (from-to)295-300
Number of pages6
JournalJournal of Organometallic Chemistry
Volume683
Issue number2
DOIs
Publication statusPublished - Oct 15 2003
Externally publishedYes

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Bearings (structural)
Fullerenes
Gadiformes
Rhodium
dienes
rhodium
fullerenes
catalytic activity
Catalyst activity
Ligands
hydroboration
ligands
Alkynes
alkynes
synthesis
adducts
X rays
X-Rays
x rays

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand. / Toganoh, Motoki; Matsuo, Yutaka; Nakamura, Eiichi.

In: Journal of Organometallic Chemistry, Vol. 683, No. 2, 15.10.2003, p. 295-300.

Research output: Contribution to journalArticle

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