Abstract
Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 295-300 |
| Number of pages | 6 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 683 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Oct 15 2003 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
Cite this
Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand. / Toganoh, Motoki; Matsuo, Yutaka; Nakamura, Eiichi.
In: Journal of Organometallic Chemistry, Vol. 683, No. 2, 15.10.2003, p. 295-300.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand
AU - Toganoh, Motoki
AU - Matsuo, Yutaka
AU - Nakamura, Eiichi
PY - 2003/10/15
Y1 - 2003/10/15
N2 - Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.
AB - Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.
UR - http://www.scopus.com/inward/record.url?scp=0142120451&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0142120451&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(03)00465-0
DO - 10.1016/S0022-328X(03)00465-0
M3 - Article
AN - SCOPUS:0142120451
VL - 683
SP - 295
EP - 300
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 2
ER -