Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand

Motoki Toganoh; Yutaka Matsuo; Eiichi Nakamura

doi:10.1016/S0022-328X(03)00465-0

Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η⁵-ligand

Motoki Toganoh, Yutaka Matsuo, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Rhodium η⁵-complexes bearing an indenyl-type fullerene ligand, Rh[C₆₀(PhCH₂)₂Ph](cod) (2), Rh[C₆₀(PhCH₂)₂Ph](nbd) (3) and Rh(C₇₀Ph₃)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.

Original language	English
Pages (from-to)	295-300
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	683
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(03)00465-0
Publication status	Published - Oct 15 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand",

abstract = "Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.",

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T1 - Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand

AU - Toganoh, Motoki

AU - Matsuo, Yutaka

AU - Nakamura, Eiichi

PY - 2003/10/15

Y1 - 2003/10/15

N2 - Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.

AB - Rhodium η5-complexes bearing an indenyl-type fullerene ligand, Rh[C60(PhCH2)2Ph](cod) (2), Rh[C60(PhCH2)2Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions.

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