Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.
|Number of pages||2|
|Publication status||Published - Jan 1 1999|
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