Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani, Shinya Nakayama, Mari Ichimura, Nobuhumi Nakamura, Yoshinori Naruta

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12 Citations (Scopus)

Abstract

Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.

Original languageEnglish
Pages (from-to)729-730
Number of pages2
JournalChemistry Letters
Issue number8
DOIs
Publication statusPublished - Jan 1 1999

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Porphyrins
Cytochrome P-450 Enzyme System
Raman scattering
Iron
Oxygen
Ligands

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450. / Tani, Fumito; Nakayama, Shinya; Ichimura, Mari; Nakamura, Nobuhumi; Naruta, Yoshinori.

In: Chemistry Letters, No. 8, 01.01.1999, p. 729-730.

Research output: Contribution to journalArticle

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