Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani; Shinya Nakayama; Mari Ichimura; Nobuhumi Nakamura; Yoshinori Naruta

doi:10.1246/cl.1999.729

Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Fumito Tani, Shinya Nakayama, Mari Ichimura, Nobuhumi Nakamura, Yoshinori Naruta

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O₂ binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O₂) band at 578 cm^-1 in the resonance Raman spectrum.

Original language	English
Pages (from-to)	729-730
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1999.729
Publication status	Published - Jan 1 1999

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1999.729

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abstract = "Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.",

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AU - Tani, Fumito

AU - Nakayama, Shinya

AU - Ichimura, Mari

AU - Nakamura, Nobuhumi

AU - Naruta, Yoshinori

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.

AB - Synthesis and characterization of an iron porphyrin axially-coordinated by thiolate were carried out in order to mimic the active center of cytochrome P-450. O2 binds reversibly to the ferrous form at -80 °C. The oxygenated complex showed a v(Fe-O2) band at 578 cm-1 in the resonance Raman spectrum.

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Synthesis and characterization of an iron porphyrin with a thiolate axial ligand and its dioxygen adduct as a model for the active center of cytochrome P-450

Abstract

All Science Journal Classification (ASJC) codes

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