Synthesis and characterization of an Ru2(III, IV) complex containing pyrophosphate bridge

Yuji Miyazato, Tohru Wada, Masaaki Ohba, Nobuyuki Matsushita

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3 Citations (Scopus)

Abstract

We prepared a new Ru2(III, IV) complex containing a pyrophosphate as the dinucleating component, by the reaction between the mononuclear complex [Ru(Me3tacn)Cl3] and Na4P2O7·10H2O in aqueous solution. Cyclic voltammetric measurement for the complex [{Ru(Me3tacn)}2(μ-O)(μ-P2O7)]PF6 (1) in aqueous solution revealed the formation of two species with higher oxidation states, such as [O=Ru(IV)Ru(IV)=O] and [O=Ru(IV)Ru(V)=O]+. Furthermore, this complex showed activity for water oxidation reaction with Ce(NH4)2(NO3)6 as the chemical oxidant in acidic aqueous solution.

Original languageEnglish
Pages (from-to)1388-1390
Number of pages3
JournalChemistry Letters
Volume45
Issue number12
DOIs
Publication statusPublished - 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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