Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis

Takatoshi Muta, Hideyuki Otsuka, Atsushi Takahara

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The authors report the hybridization of different olefin-containing polymers, chain-growth type polymer and step-growth type polymer, by olefin cross metathesis. An equal amount of olefin-containing polyester and 1,4-polybutadiene was mixed and dissolved in dichloromethane in the presence of Grubbs catalyst at room temperature. As the reaction proceeded, the melting endothermic peak of the hybrid polymer shifted to lower temperature. Finally, the melting peak was completely disappeared in DSC thermogram. The change in specific heat corresponding to the glass transition temperature of hybrid polymer was observed between each glass transition. These results indicate that the polymer scrambling reaction finally gives random copolymer consisted of butadiene unit and oligoester unit.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan - 55th SPSJ Annual Meeting
Pages193
Number of pages1
Volume55
Edition1
Publication statusPublished - 2006
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

Fingerprint

Olefins
Polymerization
Polymers
Melting
Polybutadienes
Dichloromethane
Butadiene
Specific heat
Polyesters
Glass transition
Copolymers
Temperature
Catalysts

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Muta, T., Otsuka, H., & Takahara, A. (2006). Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. In Polymer Preprints, Japan - 55th SPSJ Annual Meeting (1 ed., Vol. 55, pp. 193)

Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. / Muta, Takatoshi; Otsuka, Hideyuki; Takahara, Atsushi.

Polymer Preprints, Japan - 55th SPSJ Annual Meeting. Vol. 55 1. ed. 2006. p. 193.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Muta, T, Otsuka, H & Takahara, A 2006, Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. in Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 edn, vol. 55, pp. 193, 55th SPSJ Annual Meeting, Nagoya, Japan, 5/24/06.
Muta T, Otsuka H, Takahara A. Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. In Polymer Preprints, Japan - 55th SPSJ Annual Meeting. 1 ed. Vol. 55. 2006. p. 193
Muta, Takatoshi ; Otsuka, Hideyuki ; Takahara, Atsushi. / Synthesis and characterization of hybrid polymers prepared by step-growth polymerization and chain-growth polymerization by olefin metathesis. Polymer Preprints, Japan - 55th SPSJ Annual Meeting. Vol. 55 1. ed. 2006. pp. 193
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