Synthesis and characterization of n-fused porphyrin rhodium complex with an isomerized cyclooctadiene ligand

Jibin Alex Abraham, Shigeki Mori, Masatoshi Ishida, Hiroyuki Furuta

Research output: Contribution to journalArticlepeer-review

Abstract

A novel sandwich N-fused porphyrin rhodium complex (Rh-1-Br) comprising a brominated N-fused porphyrin (1-Br) and an isomerized cyclooctadiene ligand was synthesized and characterized. X-ray crystallographic analysis revealed a 1,5- cyclooctadiene isomerization into allylic CH activated κ1,η3- C8H12 unit bound to the Rh center. The rotational dynamics of κ1,η3-C8H12 ring in Rh-1-Br was discussed using 1HNMR spectroscopic analysis and DFT calculation.

Original languageEnglish
Pages (from-to)1707-1719
Number of pages13
JournalChemistry Letters
Volume50
Issue number9
DOIs
Publication statusPublished - Sep 2021

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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