Synthesis and characterization of the dicobalt bisporphyrin complex linked by 1,2-phenylene bridge

Yuichi Shimazaki, Hironori Takesue, Takefumi Chishiro, Fumito Tani, Yoshinori Naruta

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The structure of a 1,2-phenylene linked dicobalt tetraarylporphyrin dimer was determined by X-ray crystallography and its dioxygen adduct was characterized by absorption and ESR spectroscopies. Since the porphyrin dimer has a long metal-metal distance and a rigid framework against inward bending, the cobalt centers were not bridged by the coordinated dioxygen.

Original languageEnglish
Pages (from-to)538-539
Number of pages2
JournalChemistry Letters
Issue number6
DOIs
Publication statusPublished - Jan 1 2001

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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