Synthesis and crystal structure of 1,2,4-trifluoro-3,5,6- tris(triisopropylsilyl)benzene

Takeshi Hanamoto, Yukinori Koga, Toshio Kawanami, Hiroshi Furuno, Junji Inanaga

    Research output: Contribution to journalArticlepeer-review

    8 Citations (Scopus)

    Abstract

    Fluorinated Dewar benzene (1,2,4-trifluoro-3,5,6-tris(triisopropylsilyl) bicyclo[2,2,0]-hexa-2,5-diene) efficiently prepared from fluoro(triisopropylsilyl)acetylene was thermochemically or photochemically transformed into the corresponding highly crowded fluorinated benzene (1,2,4-trifluoro-3,5,6-tris(triisopropylsilyl)benzene) in excellent yield. The molecular structure of the crowded benzene was determined by X-ray crystallography.

    Original languageEnglish
    Pages (from-to)493-495
    Number of pages3
    JournalTetrahedron Letters
    Volume47
    Issue number4
    DOIs
    Publication statusPublished - Jan 23 2006

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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