TY - JOUR
T1 - Synthesis and crystal structure of a new water-soluble sulfur-containing palladacyclic diaqua complex
AU - Uehara, Keiji
AU - Fukuzumi, Shunichi
AU - Ogo, Seiji
N1 - Funding Information:
This work was supported by a Grant in aids (15036242, 15350033, 16655022, 17350027, 17655027, 18033041, and 18065017) from the Ministry of Education, Culture, Sports, Science and Technology, Japan, Osaka University 21st Century COE Program, and a CREST program (Nano-Structured Catalysts and Materials) by JST. We thank emeritus Professor M. Misono (University of Tokyo) for valuable discussions.
PY - 2007/1/1
Y1 - 2007/1/1
N2 - A new water-soluble sulfur-containing palladacyclic diaqua complex [(SC)PdII(H2O)2]2 (SO4) {[1]2(SO4), SC = C6H4-2-(CH2StBu)} was synthesized from a reaction of Ag2SO4 with a water-insoluble palladacyclic dichloro complex [(SC)PdII(μ-Cl)]2 (2) in water. Water-solubility of [1]2(SO4) at pH 7 at 25 °C is 9.4 mg/mL. NH4PF6 was added to the solution of [1]2(SO4) in water to give [1](PF6). The structures of [1](PF6) and 2 were unequivocally determined by X-ray analysis.
AB - A new water-soluble sulfur-containing palladacyclic diaqua complex [(SC)PdII(H2O)2]2 (SO4) {[1]2(SO4), SC = C6H4-2-(CH2StBu)} was synthesized from a reaction of Ag2SO4 with a water-insoluble palladacyclic dichloro complex [(SC)PdII(μ-Cl)]2 (2) in water. Water-solubility of [1]2(SO4) at pH 7 at 25 °C is 9.4 mg/mL. NH4PF6 was added to the solution of [1]2(SO4) in water to give [1](PF6). The structures of [1](PF6) and 2 were unequivocally determined by X-ray analysis.
UR - http://www.scopus.com/inward/record.url?scp=33845902588&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33845902588&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2006.08.088
DO - 10.1016/j.jorganchem.2006.08.088
M3 - Article
AN - SCOPUS:33845902588
SN - 0022-328X
VL - 692
SP - 499
EP - 504
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-3
ER -