Synthesis and crystal structure of a new water-soluble sulfur-containing palladacyclic diaqua complex

Keiji Uehara, Shunichi Fukuzumi, Seiji Ogo

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A new water-soluble sulfur-containing palladacyclic diaqua complex [(SC)PdII(H2O)2]2 (SO4) {[1]2(SO4), SC = C6H4-2-(CH2StBu)} was synthesized from a reaction of Ag2SO4 with a water-insoluble palladacyclic dichloro complex [(SC)PdII(μ-Cl)]2 (2) in water. Water-solubility of [1]2(SO4) at pH 7 at 25 °C is 9.4 mg/mL. NH4PF6 was added to the solution of [1]2(SO4) in water to give [1](PF6). The structures of [1](PF6) and 2 were unequivocally determined by X-ray analysis.

Original languageEnglish
Pages (from-to)499-504
Number of pages6
JournalJournal of Organometallic Chemistry
Volume692
Issue number1-3
DOIs
Publication statusPublished - Jan 1 2007

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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