Synthesis and Diels-Alder reactions of 1,2-dimethylene[2.n]metacyclophanes

Takehiko Yamato, Shinpei Miyamoto, Tohru Hironaka, Yoshinori Miura

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

(Chemical Equation Presented) The Diels-Alder reaction of 1,2-dimethylene[2.n]MCPs (MCP = metacyclophane) with suitable dienophiles followed by aromatization and photoinduced or FeCl3-induced transannular cyclization afforded phenanthrene-anellated polycyclic aromatic hydrocarbons, which were found to adopt helical chirality in the solid state.

Original languageEnglish
Pages (from-to)3-6
Number of pages4
JournalOrganic letters
Volume7
Issue number1
DOIs
Publication statusPublished - Jan 6 2005

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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