Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine

Hisanori Nagatomi, Nobuhiro Yanai, Teppei Yamada, Kanji Shiraishi, Nobuo Kimizuka

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Complexation of copper(II) 2,3,9,10,16,17,23,24-octahydroxy-29H,31H-phthalocyanine (CuPcOH) with copper(II) ions gives a two-dimensional (2D) metal-organic framework (MOF). This is the first report of a phthalocyanine-based MOF. This 2D MOF was obtained as a black powder and showed an electrical conductivity of 1.6×10−6 S cm−1 at 80 °C. When this MOF is used as a cathode of lithium ion battery (LIB), large charge/discharge capacities of 151/128 mAh g−1 were obtained. In addition, it showed a good stability during 200 charge/discharge cycles. The obtained LIB performance mainly originates from the electrically conductive and redox-active framework of the phthalocyanine-based 2D MOF and its hierarchical microporous/mesoporous structure.

Original languageEnglish
Pages (from-to)1806-1810
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number8
DOIs
Publication statusPublished - Feb 6 2018

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Electric properties
Metals
Copper
Complexation
Powders
Cathodes
phthalocyanine
Ions
Lithium-ion batteries

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine. / Nagatomi, Hisanori; Yanai, Nobuhiro; Yamada, Teppei; Shiraishi, Kanji; Kimizuka, Nobuo.

In: Chemistry - A European Journal, Vol. 24, No. 8, 06.02.2018, p. 1806-1810.

Research output: Contribution to journalArticle

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