Synthesis and electronic properties of ferrocene-containing organic dyads

Motonori Watanabe, Yuan Jay Chang, Po Ting Chou, Aleksandar Staykov, Masahiko Shibahara, Katsuya Sako, Tatsumi Ishihara, Tahsin J. Chow

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.

Original languageEnglish
Pages (from-to)1548-1551
Number of pages4
JournalTetrahedron Letters
Volume56
Issue number12
DOIs
Publication statusPublished - Mar 18 2015

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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