Synthesis and electronic properties of ferrocene-containing organic dyads

Motonori Watanabe, Yuan Jay Chang, Po Ting Chou, Aleksandar Staykov, Masahiko Shibahara, Katsuya Sako, Tatsumi Ishihara, Tahsin J. Chow

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.

    Original languageEnglish
    Pages (from-to)1548-1551
    Number of pages4
    JournalTetrahedron Letters
    Volume56
    Issue number12
    DOIs
    Publication statusPublished - Mar 18 2015

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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