TY - JOUR
T1 - Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies
AU - Ohba, Masaaki
AU - Okawa, Hisashi
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Scientific Research on Priority Area ‘Metal-assembled Complexes’ (No. 09044093) to H.O., and a Grant-in-Aid for Scientific Research (c) (No. 11640568) to M.O. from the Ministry of Education, Science, Sports and Culture, Japan.
PY - 2000
Y1 - 2000
N2 - The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.
AB - The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.
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U2 - 10.1016/S0010-8545(00)00233-2
DO - 10.1016/S0010-8545(00)00233-2
M3 - Review article
AN - SCOPUS:0033830241
VL - 198
SP - 313
EP - 328
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - 1
ER -