Abstract
The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.
| Original language | English |
|---|---|
| Pages (from-to) | 313-328 |
| Number of pages | 16 |
| Journal | Coordination Chemistry Reviews |
| Volume | 198 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 1 2000 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Cite this
Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies. / Ohba, Masaaki; Okawa, Hisashi.
In: Coordination Chemistry Reviews, Vol. 198, No. 1, 01.01.2000, p. 313-328.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies
AU - Ohba, Masaaki
AU - Okawa, Hisashi
PY - 2000/1/1
Y1 - 2000/1/1
N2 - The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.
AB - The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.
UR - http://www.scopus.com/inward/record.url?scp=0033830241&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033830241&partnerID=8YFLogxK
U2 - 10.1016/S0010-8545(00)00233-2
DO - 10.1016/S0010-8545(00)00233-2
M3 - Review article
VL - 198
SP - 313
EP - 328
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - 1
ER -