Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies

Masaaki Ohba, Hisashi Okawa

Research output: Contribution to journalReview article

712 Citations (Scopus)

Abstract

The structures and magnetism of complex-based metal assemblies derived from [M(CN)6]n- (M = Cr3+, Mn3+, Fe3+, Co3+, Fe2+; n = 3, 4) and coordinatively unsaturated [MA(L)x]m+ (MA = Mn2+, Ni2+, Cu2+, Mn3+, Fe3+; L = polyamine ligand, salen2- derivatives) are reviewed. The reaction of the constituents in different ratios, in the absence or presence of an appropriate cation or anion and by the change of ligand L provides multi-dimensional bimetallic assemblies of various networks extended through M-CN-MA-NC- linkages. The magnetic properties of the assemblies are discussed with respect to their network structures and MA/M combinations. These assemblies provide significant insights into magnetostructural correlation and design of magnetic materials.

Original languageEnglish
Pages (from-to)313-328
Number of pages16
JournalCoordination Chemistry Reviews
Volume198
Issue number1
DOIs
Publication statusPublished - Jan 1 2000

Fingerprint

Cyanides
Magnetism
cyanides
assemblies
synthesis
Ligands
ligands
Magnetic materials
Polyamines
magnetic materials
linkages
Anions
Cations
Magnetic properties
Negative ions
Positive ions
Metals
magnetic properties
anions
Derivatives

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies. / Ohba, Masaaki; Okawa, Hisashi.

In: Coordination Chemistry Reviews, Vol. 198, No. 1, 01.01.2000, p. 313-328.

Research output: Contribution to journalReview article

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