液晶鋳型-水熱処理法による低次元量子閉じ込め構造酸化物半導体の合成と光物性

Translated title of the contribution: Synthesis and Optical Properties of Low-Dimensional Quantum-Confined Oxide Semiconductors by Liquid Crystal Templating-Hydrothermal Technique

大瀧 倫卓, 三宅 こずえ

    Research output: Contribution to journalArticle

    Abstract

    Oxide semiconductors with MCM-50--like layered structures are synthesized by liquid crystal templating followed by hydrothermal treatment. The band gap energy of hydrothermal-treated lamellar TiO$_2$ shows a substantial blue shift of $Delta E_g=0.31$~eV. The thickness of the 2-dimensional TiO$_2$ sheets estimated from $Delta E_g$ by using Blus' equation describing the quantum-confinement effect agrees within a factor of 1.5 with that determined from TEM observation. A new photoluminescence peak appears at $ca.$ 380~nm, being in good accordance with the wider band gap energy of the lamellar TiO$_2$. Lamellar Fe$_2$O$_3$ and Bi$_2$O$_3$ show sharp absorption peaks at the lower energy of the absorption edges, suggesting exciton absorption observable at root temperature.
    Original languageJapanese
    Pages (from-to)359-364
    Number of pages6
    Journal九州大学大学院総合理工学報告
    Volume22
    Issue number4
    DOIs
    Publication statusPublished - Mar 30 2001

    Cite this

    液晶鋳型-水熱処理法による低次元量子閉じ込め構造酸化物半導体の合成と光物性. / 大瀧倫卓; 三宅こずえ.

    In: 九州大学大学院総合理工学報告, Vol. 22, No. 4, 30.03.2001, p. 359-364.

    Research output: Contribution to journalArticle

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    abstract = "Oxide semiconductors with MCM-50--like layered structures are synthesized by liquid crystal templating followed by hydrothermal treatment. The band gap energy of hydrothermal-treated lamellar TiO$_2$ shows a substantial blue shift of $Delta E_g=0.31$~eV. The thickness of the 2-dimensional TiO$_2$ sheets estimated from $Delta E_g$ by using Blus' equation describing the quantum-confinement effect agrees within a factor of 1.5 with that determined from TEM observation. A new photoluminescence peak appears at $ca.$ 380~nm, being in good accordance with the wider band gap energy of the lamellar TiO$_2$. Lamellar Fe$_2$O$_3$ and Bi$_2$O$_3$ show sharp absorption peaks at the lower energy of the absorption edges, suggesting exciton absorption observable at root temperature.",
    author = "倫卓 大瀧 and こずえ 三宅",
    year = "2001",
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