Synthesis and Optical Properties of Thiazolo-Chlorin and Porphyrin Skeletons

Takeo Nakano, Hiroaki Imoto, Kensuke Naka

Research output: Contribution to journalArticlepeer-review

Abstract

Macrocyclic π-skeletons containing a thiazole moiety were synthesized via MacDonald [3 + 1]-type condensation. The construction of thiazolochlorin 1a and thiazoloporphyrin 1b depended on the conformation of the thiazole moieties, and their 18π-systems expanded along the molecular y and x axes, respectively. In particular, the structure of thiazolochlorin 1a was studied in detail using 2D nuclear magnetic resonance methods. The optical properties in solution were measured and discussed based on both experimental data and computational studies.

Original languageEnglish
Pages (from-to)7996-8000
Number of pages5
JournalOrganic letters
Volume23
Issue number20
DOIs
Publication statusPublished - Oct 15 2021

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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