Synthesis and photochemical properties of a new molybdenum porphycene complex

Daisuke Maeda, Hisashi Shimakoshi, Masaaki Abe, Yoshio Hisaeda

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    14 Citations (Scopus)

    Abstract

    A new molybdenum porphycene complex, which is a new complex having oxo and chloro groups at the axial positions, was successfully synthesized. This chloro(oxo)molybdenum(v) complex, [MoV(OEPc)(O)Cl] (1) has strong absorption bands in the visible region attributed to the properties of the porphycene and is very attractive from a photochemical viewpoint. This complex was readily reduced from Mo(v) to Mo(iv) species to yield [Mo IV(OEPc)(O)] under anaerobic irradiation by visible light. This photochemical reaction mechanism is derived from the homolytic cleavage of the axial ligand. Furthermore, this photochemical reduction proceeded very effectively compared to that for the corresponding porphyrin complex.

    Original languageEnglish
    Pages (from-to)140-145
    Number of pages6
    JournalDalton Transactions
    Issue number1
    DOIs
    Publication statusPublished - Jan 1 2009

    All Science Journal Classification (ASJC) codes

    • Inorganic Chemistry

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