TY - JOUR
T1 - Synthesis and properties of a mercapto[15]annulenone
T2 - A 14π diatropic annulene triply characterised by a fast chemical exchange, tautomerisation, and cis-trans-isomerisation
AU - Ogawa, Haru
AU - Yoshikawa, Masashi
AU - Tanaka, Hiroyuki
AU - Imoto, Taiji
AU - Miyamoto, Izumi
AU - Kato, Hidefumi
AU - Taniguchi, Yoichi
AU - Nogami, Yasuyoshi
AU - Koga, Toshitaka
PY - 1989
Y1 - 1989
N2 - Mercapto[15]annulenone (4) has been prepared from annulenone (2) as a tautomeric mixture with the keto-tautomer (5) in 65% yield; it was found that (4) proved to be diatropic and exists as a rapid equilibrium mixture of (4a) and (4b).
AB - Mercapto[15]annulenone (4) has been prepared from annulenone (2) as a tautomeric mixture with the keto-tautomer (5) in 65% yield; it was found that (4) proved to be diatropic and exists as a rapid equilibrium mixture of (4a) and (4b).
UR - http://www.scopus.com/inward/record.url?scp=37049079098&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049079098&partnerID=8YFLogxK
U2 - 10.1039/C39890000505
DO - 10.1039/C39890000505
M3 - Article
AN - SCOPUS:37049079098
SN - 1359-7345
SP - 505
EP - 507
JO - Chemical Communications
JF - Chemical Communications
IS - 8
ER -