Synthesis and properties of alkylperoxocobalt(III) porphyrin and porphycene

Takashi Hayashi, Kenshi Okazaki, Hisashi Shimakoshi, Fumito Tani, Yoshinori Naruta, Yoshio Hisaeda

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Alkylcobalt(III) and alkylperoxocobalt(III) species of porphyrin and porphycene have been prepared and characterized by UV-vis and 1H NMR spectroscopic measurements. Thermal decomposition of the alkylperoxocobalt species proceeds via Co-O or O-O bond cleavage, which depends on the coordination of an axial ligand.

Original languageEnglish
Pages (from-to)90-91
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - Jan 1 2000

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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