Synthesis and radical polymerization of acrylamides having one or two 3-carbazolylmethyl moieties and properties of the formed polymers

Keita Tani, Haruka Kato, Naoya Sakata, Toru Yashima, Koji Kubono, Kazushige Hori, Keisuke Tao, Kenta Goto, Fumito Tani, Hiroyuki Takemura, Keita Sakakibara, Yoshinobu Tsujii

Research output: Contribution to journalArticle

Abstract

A series of novel mono- and bis[(9-alkylcarbazol-3-yl)methyl]acrylamides were synthesized and their radical polymerization was investigated. Emissions of bis(carbazolyl)acrylamide polymers were extended to longer wavelengths compared with those of the corresponding mono(carbazolyl) polymers, indicating the existence of interchromophoric interaction between carbazole moieties. Ionization potentials of the polymers by photoelectron yield spectroscopy showed that donor ability of the biscarbazolyl polymer was higher than that of the monocarbazolyl polymer.

Original languageEnglish
Pages (from-to)85-87
Number of pages3
JournalChemistry Letters
Volume46
Issue number1
DOIs
Publication statusPublished - Jan 1 2017

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Acrylamides
Free radical polymerization
Polymers
Ionization potential
Acrylamide
Photoelectrons
Spectroscopy
Wavelength

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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Synthesis and radical polymerization of acrylamides having one or two 3-carbazolylmethyl moieties and properties of the formed polymers. / Tani, Keita; Kato, Haruka; Sakata, Naoya; Yashima, Toru; Kubono, Koji; Hori, Kazushige; Tao, Keisuke; Goto, Kenta; Tani, Fumito; Takemura, Hiroyuki; Sakakibara, Keita; Tsujii, Yoshinobu.

In: Chemistry Letters, Vol. 46, No. 1, 01.01.2017, p. 85-87.

Research output: Contribution to journalArticle

Tani, K, Kato, H, Sakata, N, Yashima, T, Kubono, K, Hori, K, Tao, K, Goto, K, Tani, F, Takemura, H, Sakakibara, K & Tsujii, Y 2017, 'Synthesis and radical polymerization of acrylamides having one or two 3-carbazolylmethyl moieties and properties of the formed polymers', Chemistry Letters, vol. 46, no. 1, pp. 85-87. https://doi.org/10.1246/cl.160899
Tani, Keita ; Kato, Haruka ; Sakata, Naoya ; Yashima, Toru ; Kubono, Koji ; Hori, Kazushige ; Tao, Keisuke ; Goto, Kenta ; Tani, Fumito ; Takemura, Hiroyuki ; Sakakibara, Keita ; Tsujii, Yoshinobu. / Synthesis and radical polymerization of acrylamides having one or two 3-carbazolylmethyl moieties and properties of the formed polymers. In: Chemistry Letters. 2017 ; Vol. 46, No. 1. pp. 85-87.
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