Synthesis and reactions of 5-tributylstannyl-4-fluoro-1H-pyrazole

Takeshi Hanamoto, Takao Suetake, Yukinori Koga, Toshio Kawanami, Hiroshi Furuno, Junji Inanaga

    Research output: Contribution to journalArticlepeer-review

    23 Citations (Scopus)

    Abstract

    The palladium-catalyzed cross-coupling reactions of 5-tributylstannyl-4-fluoro-1H-pyrazole with aryl iodides provided high yields of the corresponding 5-aryl-4-fluoro-1H-pyrazoles. Furthermore, these cross-coupling reactions proceeded smoothly under an atmosphere of carbon monoxide (CO) to afford the corresponding 5-acyl-4-fluoro-1H-pyrazoles as CO-insertion products.

    Original languageEnglish
    Pages (from-to)5062-5070
    Number of pages9
    JournalTetrahedron
    Volume63
    Issue number23
    DOIs
    Publication statusPublished - Jun 4 2007

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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